JAMIA MILLIA ISLAMIA Jamia Millia Islamia Solved Paper-2007

  • question_answer
        The enthalpies of combustion of carbon and carbon monoxide are\[-393.5\]and\[-283k\text{ }J\] \[mo{{l}^{-1}}\]respectively. The enthalpy of formation of carbon monoxide per mole is

    A)  110.5kJ                               

    B)  676.5 kJ

    C)  \[-676.5\text{ }kJ\]        

    D) \[-110.5kJ\]

    Correct Answer: D

    Solution :

                    I: \[C(s)+{{O}_{2}}(g)\xrightarrow[{}]{{}}C{{O}_{2}}(g)\]\[\Delta H=-393.5\,kJ\] II: \[CO(g)+\frac{1}{2}{{O}_{2}}(g)\xrightarrow[{}]{{}}C{{O}_{2}}(g),\]                                                 \[\Delta H=-283.0\,kJ\] \[I-II\] gives III:\[C(s)+\frac{1}{2}{{O}_{2}}(g)\xrightarrow[{}]{{}}CO(g),\] \[\Delta H=-110.5\,kJ\] This equation III also represents formation of one mol of CO and thus enthalpy change is the heat of formation of CO (g).


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