JAMIA MILLIA ISLAMIA Jamia Millia Islamia Solved Paper-2012

  • question_answer
    The product formed in the reaction n-hexanamide\[+B{{r}_{2}}+KOH,\]is

    A)  hexanamine                     

    B)  propanamme

    C)  butanamine     

    D)  pentanamme

    Correct Answer: D

    Solution :

                    When amide is heated with a mixture of\[B{{r}_{2}}\]in the presence of\[NaOH\]or KOH, amine is formed which has one carbon atom less than original amide. This is called Hofmanns degradation reaction. \[Hexanamide+B{{r}_{2}}+4KOH\xrightarrow{{}}Pentanamine\] \[+{{K}_{2}}C{{O}_{3}}+2KBr+2{{H}_{2}}O\]


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