JAMIA MILLIA ISLAMIA Jamia Millia Islamia Solved Paper-2013

  • question_answer
    Enthalpy of neutralization of\[HF(aq)\]\[HF(aq)+O{{H}^{-}}(aq)\xrightarrow[{}]{{}}{{F}^{-}}(aq)+{{H}_{2}}O(l)\]is \[-68.60\,kJ\,mo{{l}^{-1}}\]and enthalpy change for the reaction is\[-55.83\text{ }kJ\,mo{{l}^{-1}}\].\[{{H}^{+}}(aq)+O{{H}^{-}}(aq)\xrightarrow[{}]{{}}{{H}_{2}}O(l)\] Thus, enthalpy change \[(kJ\,mo{{l}^{-1}})\] for the dissociation is\[HF(aq)\xrightarrow[{}]{{}}{{H}^{+}}(aq)+{{F}^{-}}(aq)\]

    A)  \[-12.77\]                          

    B)  \[+12.77\]

    C)  \[-124.43\]                        

    D)  \[+124.43\]

    Correct Answer: B

    Solution :

                    \[HF(aq)\xrightarrow[{}]{{}}{{H}^{+}}(aq)+O{{H}^{-}}(aq)\] \[\Delta H=-68.60-(-55.83)=-12.77\text{ }kJ\,mo{{l}^{-1}}\]


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