A) \[C{{H}_{3}}C{{H}_{2}}N{{H}_{2}}\]
B) \[{{C}_{6}}{{H}_{5}}CN\]
C) \[C{{H}_{3}}C{{H}_{2}}NC\]
D) \[{{C}_{2}}{{H}_{5}}CN\]
Correct Answer: C
Solution :
Key Idea: This is carbyl amine reaction. In this reaction bad smelling isocyanide is formed by reaction of \[{{1}^{o}}\] amine with \[CHC{{l}_{3}}\] and\[~KOH\]. So isocyanide is correct answer. \[\underset{\begin{smallmatrix} (a) \\ {{1}^{o}}\text{amine} \end{smallmatrix}}{\mathop{C{{H}_{3}}C{{H}_{2}}N{{H}_{2}}}}\,\]\[\underset{\begin{smallmatrix} (b) \\ cynide \end{smallmatrix}}{\mathop{{{C}_{6}}{{H}_{5}}CN}}\,\]\[\underset{\begin{smallmatrix} (c) \\ isocyanide \end{smallmatrix}}{\mathop{C{{H}_{3}}C{{H}_{2}}NC}}\,\]\[\underset{\begin{smallmatrix} (d) \\ cyanide \end{smallmatrix}}{\mathop{{{C}_{2}}{{H}_{5}}CN}}\,\]
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