JCECE Engineering JCECE Engineering Solved Paper-2002

  • question_answer
    \[A+NaOH\xrightarrow{{}}C{{H}_{3}}OH+HCOONa\]is the reaction, compound \[A\] is:

    A) \[HCN\]                               

    B) \[HCHO\]

    C) \[C{{H}_{3}}CN\]                             

    D)  \[C{{H}_{3}}Cl\]

    Correct Answer: B

    Solution :

    Key Idea: This is Cannizaro reaction. In this reaction aldehydes, which do not have \[\alpha -\]hydrogen atom undergo disproportionation reaction, half of the molecule are reduced and other half are oxidised. \[\underset{(A)}{\mathop{HCHO}}\,+NaOH\xrightarrow{{}}\underset{sodium\,\,formate}{\mathop{HCOONa}}\,\]\[\underset{methyl\,\,alcohol}{\mathop{+C{{H}_{3}}OH}}\,\]


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