JCECE Engineering JCECE Engineering Solved Paper-2006

  • question_answer
    When acetamide is reacted with \[NaOBr\], then product formed is:

    A)  ethanamine     

    B)  methanamine

    C)  methanamide                 

    D)  ethanenitrile

    Correct Answer: B

    Solution :

    When acetamide is treated with \[NaBr\] or \[B{{r}_{2}}/NaOH\], Hofmann degradation reaction takes place and a primary amine is obtained as: \[C{{H}_{3}}CONH+NaOBr\]or\[B{{r}_{2}}/NaOH\xrightarrow{{}}\] \[\underset{\begin{smallmatrix}  \text{methyl}\,\,\text{amine} \\  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,or  \\  \text{methanamine} \end{smallmatrix}}{\mathop{C{{H}_{3}}N{{H}_{2}}}}\,+2NaBr+NaHC{{O}_{3}}+{{H}_{2}}O\]


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