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JCECE Engineering JCECE Engineering Solved Paper-2012

  • question_answer
    \[[Co{{(N{{H}_{3}})}_{4}}C{{l}_{2}}]N{{O}_{2}}\]and\[[Co{{(N{{H}_{3}})}_{4}}ClN{{O}_{2}}]Cl\] exhibit which type is isomerism?

    A)  Geometrical                     

    B)  Optical

    C)  Linkage               

    D)  lonisation

    Correct Answer: D

    Solution :

    Both give different ions when subjected to ionisation. \[[Co{{(N{{H}_{3}})}_{4}}C{{l}_{2}}]N{{O}_{2}}\xrightarrow{{}}\]  \[{{[Co{{(N{{H}_{3}})}_{4}}C{{l}_{2}}]}^{+}}+NO_{2}^{-}\] \[[Co{{(N{{H}_{3}})}_{4}}ClN{{O}_{2}}]Cl\to {{[Co{{(N{{H}_{3}})}_{4}}ClN{{O}_{2}}]}^{+}}+C{{l}^{-}}\]They exhibit ionisadon isomerism.


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