JCECE Medical JCECE Medical Solved Paper-2002

  • question_answer
    \[5SO_{2}^{-}+2MnO_{4}^{-}+6{{H}^{+}}\xrightarrow{{}}5SO_{4}^{2-}\]\[+\,2M{{n}^{2+}}+2{{H}_{2}}O\] the oxidation number of Mn changes from:

    A) \[+\,14\,\text{to}+4\]

    B)  \[+\,6\,\text{to}+2\]

    C) \[-7\,\text{to}-2\]

    D)  \[+7\,\text{to}+2\]

    Correct Answer: D

    Solution :

     Key Idea: The sum of oxidation number of all elements in an ion is equal to charge on ion. In the reaction \[\text{MnO}_{4}^{-}\]changes into \[\text{M}{{\text{n}}^{\text{2+}}}\] Let oxidation state of Mn in \[\text{MnO}_{4}^{-}=x\] \[\therefore \] \[x+(4x-2)=-1\] \[\therefore \] \[x=+\,7\] Oxidation state of Mn in\[M{{n}^{2+}}=+\,2\] \[\therefore \]the oxidation number of Mn changes from + 7  to +2 during reaction.


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