JCECE Medical JCECE Medical Solved Paper-2010

  • question_answer
    The emf of the cell, \[Ni|N{{i}^{2+}}(1.0\,M)||A{{u}^{3+}}(1.0M)|Au\]is \[[{{E}^{o}}(N{{i}^{2+}}/Ni)=-0.25Vand\,{{E}^{o}}\]\[[A{{u}^{3+}}/Au)=+1.5V]\]

    A)  2.00 V          

    B)  1.25 V

    C)  -1.25 V         

    D)  1.75 V

    Correct Answer: D

    Solution :

     For the cell, \[\text{Ni }\!\!|\!\!\text{ N}{{\text{i}}^{2+}}\text{ }\!\!|\!\!\text{  }\!\!|\!\!\text{ A}{{\text{u}}^{3+}}|Au\] Given, \[E_{N{{i}^{2+}}/Ni}^{o}=-0.25\,V\] \[E_{A{{u}^{3+}}/Au}^{o}=+\,1.5\,V\] Here \[Ni\]I anode and Au  is cathode. \[\therefore \] \[{{E}_{cell}}={{E}_{C}}-{{E}_{A}}\] \[=1.5-(-0.25)\] \[=1.5+0.25\] \[=1.75\,V\]


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