JCECE Medical JCECE Medical Solved Paper-2011

  • question_answer
    Which of the following carbocation is most stable?

    A) \[C{{H}_{3}}\overset{+}{\mathop{C}}\,{{H}_{2}}\]

    B)  \[C{{H}_{2}}=\overset{+}{\mathop{C}}\,H\]

    C)  \[CH={{C}^{+}}\]

    D)  \[{{C}_{6}}H_{5}^{+}\]

    Correct Answer: A

    Solution :

     The electronegativity of the carbon carrying the positive charge is maximum in \[\text{HC }\!\!{}^\text{o}\!\!\text{ }{{\text{C}}^{\text{+}}}\] followed by \[{{\text{C}}_{\text{6}}}\text{H}_{\text{5}}^{\text{+}}\text{,C}{{\text{H}}_{\text{2}}}\text{=}\,{{\text{H}}^{\text{+}}}\]and least in\[\text{C}{{\text{H}}_{\text{3}}}\overset{\text{+}}{\mathop{\text{C}}}\,{{\text{H}}_{\text{2}}}\text{.}\] Higher the electronegativity, lesser the stability. Thus, \[\text{C}{{\text{H}}_{\text{3}}}\overset{\text{+}}{\mathop{\text{C}}}\,{{\text{H}}_{\text{2}}}\]is the most Stable carbocation.


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