question_answer3) The increasing order of the rate of\[HCN\] addition to compounds I-IV is (A)\[HCHO\] (B)\[C{{H}_{3}}COC{{H}_{3}}\] (C)\[PhCOC{{H}_{3}}\] (D)\[PhCOPh\]
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question_answer4) How many moles of magnesium phosphate, \[M{{g}_{3}}{{(P{{O}_{4}})}_{2}}\]will contain 0.25 mole of oxygen atoms?
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question_answer8) A reaction was found to be second order with respect to the concentration of carbon monoxide. If the concentration of carbon monoxide is doubled, with everything else kept the same, the rate of reaction will
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question_answer12) In the transformation of\[_{92}^{238}U\]to\[_{92}^{234}U\], if one emission is an \[\alpha \]-particle, what should be the other emission (s)?
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question_answer14) \[C{{H}_{3}}Br+N{{u}^{-}}\to C{{H}_{3}}-Nu+B{{r}^{-}}\] The decreasing order of the rate of the above reaction with nucleophiles \[(N{{u}^{-}})A\] to IV is \[[N{{u}^{-}}=(A)\,Ph{{O}^{-}},\,(B)\,Ac{{O}^{-}},\,(C)\,H{{O}^{-}},\,(D)\,C{{H}_{3}}{{O}^{-}}]\]
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question_answer18) Uncertainty in the position of an electron (mass\[=9.1\times {{10}^{-31}}kg\]) moving with a velocity\[300\text{ }m{{s}^{-1}},\] accurate upon 0.001% will be\[(h=6.63\times {{10}^{-34}}Js)\])
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question_answer19) Phosphorus pentachloride dissociates as follows, in a closed reaction vessel, \[PC{{l}_{5}}(g)PC{{l}_{3}}(g)+C{{l}_{2}}(g)\] If total pressure at equilibrium of the reaction mixture is p and degree of dissociation of \[PC{{l}_{5}}\] is\[x\], the partial pressure of\[PC{{l}_{3}}\]will be
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question_answer20) The standard enthalpy of formation \[(\Delta H_{f}^{o})\] at 298 K for methane,\[C{{H}_{4}}(g),\]is \[-74.8\text{ }kJ\text{ }mo{{l}^{-1}}\] The additional information required to determine the average energy for\[CH\] bond formation would be
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A)
the dissociation energy of Hg and enthalpy of sublimation of carbon
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B)
latent heat of vaporisation of methane
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C)
the first four ionisation energies of carbon and electron gain enthalpy of hydrogen
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D)
the dissociation energy of hydrogen molecule,\[{{H}_{2}}\]
question_answer23) A metal, M forms chlorides in its +2 and +4 oxidation states. Which of the following statements about these chlorides is correct?
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A)
\[MC{{l}_{2}}\] is more volatile than\[MC{{l}_{4}}\]
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B)
\[MC{{l}_{2}}\]is more soluble in anhydrous ethanol than\[MC{{l}_{4}}\]
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C)
\[MC{{l}_{2}}\]is more ionic than\[MC{{l}_{4}}\]
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D)
\[MC{{l}_{2}}\]is more easily hydrolysed than\[MC{{l}_{4}}\]
question_answer25) The molar conductivities \[\hat{\ }_{NaOAc}^{o}\]and \[\hat{\ }_{HCl}^{o}\]at infinite dilution in water at\[25{}^\circ C\]are 91.0 and \[426.2\text{ }S\text{ }c{{m}^{2}}/mol\]respectively. To calculate \[\hat{\ }_{HOAc'}^{o}\]the additional value required is
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question_answer27) The correct order of increasing acid strength of the compounds
(I) \[C{{H}_{3}}C{{O}_{2}}H\]
(II) \[MeOC{{H}_{2}}C{{O}_{2}}H\]
(III) \[C{{F}_{3}}C{{O}_{2}}H\]
(IV)
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question_answer30) Nickel\[(Z=28)\]combines with a uninegative monodentate ligand\[{{X}^{-}}\]to form a paramagnetic complex\[{{[Ni{{X}_{4}}]}^{2-}}\]. The number of unpaired electron (s) in the nickel and geometry of this complex ion are, respectively
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question_answer33) An ideal gas is allowed to expand both reversibly and irreversibly in an isolated system. If\[{{T}_{i}}\]is the initial temperature and\[{{T}_{f}}\]is the final temperature, which of the following statements is correct?
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A)
\[{{({{T}_{f}})}_{irrev}}>{{({{T}_{f}})}_{rev}}\]
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B)
\[{{T}_{f}}>{{T}_{i}}\]for reversible process but\[{{T}_{f}}={{T}_{i}}\]for irreversible process
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C)
\[{{({{T}_{f}})}_{rev}}={{({{T}_{i}})}_{irrev}}\]
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D)
\[{{T}_{f}}={{T}_{i}}\]for both reversible and irreversible processes
question_answer35) Rate of a reaction can be expressed by Arrhenius equation as \[k=A{{e}^{-E/RT}}\] In this equation, E represents
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A)
the energy above which all the. Colliding molecules will react
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B)
the energy below which colliding molecules will not react
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C)
the total energy of the reacting molecules at a temperature, T
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D)
the fraction of molecules with energy greater than the activation energy of the reaction
question_answer38) Increasing order of stability among the three main conformations (i.e.. Eclipse, Ami, Gauche) of 2-fluoroethanol is
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question_answer40) The decreasing values of bond angles from\[N{{H}_{3}}(107{}^\circ )\]to\[Sb{{H}_{3}}(91{}^\circ )\]down group-15 of the periodic table is due to
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question_answer42) The 'spin-only' magnetic moment [in units of Bohr magneton,\[({{\mu }_{\beta }})]\]of\[N{{i}^{2+}}\]in aqueous solution would be (Atomic number of\[Ni=28\])
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question_answer43) The equilibrium constant for the reaction \[S{{O}_{3}}(g)S{{O}_{2}}(g)+\frac{1}{2}{{O}_{2}}(g)\] is\[{{K}_{c}}=4.9\times {{10}^{-2}}\]. The value of\[{{K}_{c}}\]for the reaction \[2S{{O}_{2}}(g)+{{O}_{2}}(g)2S{{O}_{3}}(g)\]will be
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question_answer44) Following statements regarding the periodic trends of chemical reactivity of the alkali metals and the halogens are given. Which of these statements gives the correct picture?
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A)
The reactivity decreases in the alkali metals but increases in the halogens with increase in atomic number down the group
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B)
In both the alkali metals and the halogens, the chemical reactivity decreases with increase in atomic number down the group
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C)
Chemical reactivity increases with increase in atomic number down the group in both the alkali metals and halogens
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D)
In alkali metals, the reactivity increases but in the halogens it decreases with increase in atomic number down the group
question_answer45) Given the data at\[25{}^\circ C,\] \[Ag+{{I}^{-}}\xrightarrow{{}}AgI+{{e}^{-}};\] \[E{}^\circ =0.152\text{ }V\] \[Ag\xrightarrow{{}}A{{g}^{+}}+{{e}^{-}};\] \[E{}^\circ =-0.800\text{ }V\] What is the value of\[\log \text{ }{{K}_{sp}}\]for\[AgI\]? \[\left( 2.303\frac{RT}{F}=0.059\,V \right)\]
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question_answer46) The following mechanism has been proposed for the reaction of\[NO\]with\[B{{r}_{2}}\]to form\[NOBr\]. \[NO(g)+B{{r}_{2}}(g)NOB{{r}_{2}}(g)\] \[NOB{{r}_{2}}(g)+NO(g)\xrightarrow{{}}2NOBr(g)\] If the second step is the rate determining step, the order of the reaction with respect to\[NO(g)\]is
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question_answer48) Resistance of a conductivity cell filled with a solution of an electrolyte of concentration 0.1 M is\[100\text{ }\Omega \]. The conductivity of this solution is\[1.29\text{ }S\text{ }{{m}^{-1}}\].Resistance of the same cell when filled with 0.2 M of the same solution is\[520\,\Omega \]The molar conductivity of 0.02 M solution of the electrolyte will be
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question_answer50) Density of a 2.05 M solution of acetic acid in water is\[1.02\text{ }g/mL\]. The molality of the solution is
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question_answer51) The enthalpy changes for the following processes are listed below \[C{{l}_{2}}(g)=2Cl(g)\] \[242.3\text{ }kJ\text{ }mo{{l}^{-1}}\] \[{{I}_{2}}(g)=2I(g),\] \[151.0\text{ }kJ\text{ }mo{{l}^{-1}}\] \[ICl(g)=I(g)+Cl(g),\] \[211.3\text{ }kJ\text{ }mo{{l}^{-1}}\] \[{{I}_{2}}(s)={{I}_{2}}(g),\] \[62.76\text{ }kJ\text{ }mo{{l}^{-1}}\] Given that the standard states for iodine and chlorine are\[{{I}_{2}}(s)\]and\[C{{l}_{2}}(g)\], the standard enthalpy of formation of \[ICl\,(g)\] is
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question_answer52) How many EDTA (ethylenediaminetetra acetic acid) molecules are required to make an octahedral complex with a \[C{{a}^{2+}}\] ion ?
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question_answer54) 18 g of glucose\[({{C}_{6}}{{H}_{12}}{{O}_{6}})\]is added to 178.2 g of water. The vapour pressure of water for this aqueous solution at\[100{}^\circ C\]is
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question_answer55) \[(\Delta H-\Delta U)\]for the formation of carbon monoxide (CO) from its elements at 298 K is\[(R=8.314J{{K}^{-1}}mo{{l}^{-1}})\]
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