Solved papers for JEE Main & Advanced JEE Main Online Paper (Held On 23 April 2013)

done JEE Main Online Paper (Held On 23 April 2013) Total Questions - 30

  • question_answer1) Which of the following polymer is a polyamide?     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                     Terylene                            

    B)
                                             Nylon

    C)
                                             Rubber                              

    D)
                                             vulcanized rubber

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  • question_answer2)                 The magnetic moment of the complex anion \[{{[\operatorname{Cr}(\operatorname{NO})(\operatorname{N}{{\operatorname{H}}_{3}})(\operatorname{C}{{\operatorname{N}}_{4}})]}^{2-}}\]is:     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                      5.91 BM                             

    B)
                                             3.87 BM

    C)
                                             1.73 BM                             

    D)
                                             2.82 BM

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  • question_answer3) Glycosidic linkage is actually an:     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
     Carbonyl bond

    B)
                            Ether bond       

    C)
                           Ester bond                         

    D)
                           Amide bond

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  • question_answer4)                 Equimolar solution of the following compounds are prepared separately in water. Which will have the lowest pH value?     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                     \[\operatorname{Be}{{\operatorname{CI}}_{2}}\]

    B)
                                            \[\operatorname{Sr}{{\operatorname{CI}}_{2}}\]

    C)
                                            \[\operatorname{Ca}{{\operatorname{CI}}_{2}}\]                         

    D)
                                            \[{{\operatorname{M}}_{g}}{{\operatorname{CI}}_{2}}\]

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  • question_answer5)                 The numbers of protons, electrons and neutrons in molecule of heavy water are respectively:     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                      8,10,11                               

    B)
                                             10,10,10

    C)
                                             10,11,10                            

    D)
                                             11,10,10

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  • question_answer6)                 Number of atoms in the following samples of substances is the largest in:     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                      4.0 g of hydrogen          

    B)
                                             71.0g chlorine

    C)
                                             127.0 g of iodine            

    D)
                                             48.0g magnesium

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  • question_answer7)                 Which has bipyramidal shape?     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                     \[\operatorname{X}{{\operatorname{eOF}}_{4}}\]                       

    B)
                                            \[\operatorname{X}{{\operatorname{eO}}_{3}}\]

    C)
                                            \[\operatorname{X}{{\operatorname{eO}}_{3}}{{\operatorname{F}}_{2}}\]                     

    D)
                                            \[\operatorname{X}\operatorname{eO}{{\operatorname{F}}_{2}}\]

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  • question_answer8)                 Which is the correct order of second ionization potential of C,N, O and F in the following ?     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                     \[\operatorname{O}>\operatorname{N}>\operatorname{F}>C\]          

    B)
                                            \[O>\operatorname{F}>\operatorname{N}>C\]

    C)
                                            \[\operatorname{F}>\operatorname{O}>\operatorname{N}>C\]          

    D)
                                            \[\operatorname{C}>\operatorname{N}>\operatorname{O}>\operatorname{F}\]

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  • question_answer9)                 Natural glucose is termed D-glucose because:     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                     \[-OH\]on the second carbon is on the right side in Fischer projection

    B)
                                            \[-OH\]n the sixth carbon is on the right side in Fischer projection

    C)
                                            \[-OH\]on the fifth carbon is on the right side in Fischer projection

    D)
                                             It is dextrorotatory

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  • question_answer10)                 The shape of \[\operatorname{IF}_{6}^{-}\]is :     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                     Trgonally distorted octahedron

    B)
                                             pyramidal         

    C)
                                             Octahedral

    D)
                                             Square antiprism

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  • question_answer11)                 \[{{\operatorname{N}}_{2}}(g)+3{{\operatorname{H}}_{2}}(g)\rightleftharpoons 2{{\operatorname{NH}}_{3}}(g),{{\operatorname{K}}_{1}}\]                                      [A]                          \[{{\operatorname{N}}_{2}}(g)+{{O}_{2}}(g)\rightleftharpoons 2NO(g),{{\operatorname{K}}_{2}}\]                        [B]                 \[{{H}_{2}}(g)+\frac{1}{2}{{O}_{2}}(g)\rightleftharpoons {{H}_{2}}O(g),{{\operatorname{K}}_{3}}\]                          [C]                 The equation for the equilibrium constant of the reaction \[2{{\operatorname{NH}}_{3}}(g)+\frac{5}{2}{{O}_{2}}(g)\rightleftharpoons \]\[2\operatorname{NH}O(g)+3{{\operatorname{H}}_{3}}\operatorname{O}(g),({{K}_{4}})\] in terms of \[{{K}_{1}},{{K}_{2}},\] and \[{{K}_{3}}\]is :     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                     \[\frac{{{\operatorname{K}}_{1}}{{\operatorname{K}}_{2}}}{{{\operatorname{K}}_{3}}}\]                        

    B)
                                            \[\frac{{{\operatorname{K}}_{1}}\operatorname{K}_{3}^{2}}{{{\operatorname{K}}_{2}}}\]

    C)
                                            \[{{\operatorname{K}}_{1}}{{\operatorname{K}}_{2}}{{\operatorname{K}}_{3}}\]                         

    D)
                                            \[\frac{{{\operatorname{K}}_{2}}\operatorname{K}_{3}^{3}}{{{\operatorname{K}}_{1}}}\]

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  • question_answer12)                 \[{{\operatorname{H}}_{1}}-\]Receptor antagonists is a term associated with:     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                     Antisptics                          

    B)
                                             Anti his tam ins

    C)
                                             Antacids                            

    D)
                                             Analgesics

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  • question_answer13)                 The correct order of viscosity of the following liquids will be:     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                      Water < methyl alcohol < dimethyl ether < glycerol

    B)
                                             methyl alcohol < glycerol < water < dimethyl ether

    C)
                                             dimethyl ether < methyl alcohol < water < glycerol

    D)
                                             glycerol< dimethyl ether < water < methyl alcohol

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  • question_answer14)                 What is the ­­\[\operatorname{p}\operatorname{H}\] of a\[{{10}^{-4}}\] M \[{{\operatorname{OH}}^{-}}\] solution at \[330\operatorname{K},\] if \[{{\operatorname{K}}_{w}}\]at 330K is \[{{10}^{-13.6}}?\]     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                      4                                           

    B)
                                             9.0

    C)
                                             10                                        

    D)
                                             9.6

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  • question_answer15)                 The order of reactivity of the given haloalkanes towards nuclephlile is:     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                     \[R\,I<R\,Br<R\,Cl\]      

    B)
                                            \[R\,\,Cl>R\,\,Br>R\,\,I\]

    C)
                                            \[R\,\,Br>R\,\,Cl>R\,\,I\]            

    D)
                                            \[R\,\,Br>R\,\,I\,\,>\,R\,\,Cl\]

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  • question_answer16)                 Identify the incorrect statement:     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                      In\[{{(\operatorname{S}{{\operatorname{i}}_{3}}{{\operatorname{O}}_{9}})}^{6-}}\], tetrahedral \[Si{{O}_{4}}\] units share two oxygen atoms.

    B)
                                            Trialkylchlorosilaneon hydrolysis gives \[{{R}_{3}}SiOH\]

    C)
                                            \[SiC{{l}_{4}}\]undergoes hydrolysis to give \[{{H}_{4}}Si{{O}_{4}}\]

    D)
                                            \[{{(\operatorname{S}{{\operatorname{i}}_{3}}{{\operatorname{O}}_{9}})}^{6-}}\]has cyclic structure

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  • question_answer17)                 When a small amount of \[\operatorname{K}\operatorname{M}\operatorname{n}{{\operatorname{O}}_{4}}\]is added to concentrated\[{{\operatorname{H}}_{2}}\operatorname{S}{{\operatorname{O}}_{4}},\] a green oily compound is obtained which is highly explosive in nature. Compound may be:     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                     \[\operatorname{M}\operatorname{n}\operatorname{S}{{\operatorname{O}}_{4}}\]                               

    B)
                                            \[\operatorname{M}{{\operatorname{n}}_{2}}{{\operatorname{O}}_{7}}\]

    C)
                                            \[\operatorname{M}\operatorname{n}{{\operatorname{O}}_{2}}\]                    

    D)
                                            \[\operatorname{M}{{\operatorname{n}}_{2}}{{\operatorname{O}}_{3}}\]

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  • question_answer18) The reaction of phenol with benzoyl benzoateis known as :     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
    Claisen reaction

    B)
     Schotten-Baumann reaction

    C)
    Reimer - Tiemeann reaction

    D)
    Gatterman- Koch reaction

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  • question_answer19) ­­                Identify incorrect statement:     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                     \[C{{u}_{2}}O\] is colourless      

    B)
                                            Cupper (I) compounds

    C)
                                             Copper (I) compounds are diamagnetic

    D)
                                            \[{{\operatorname{Cu}}_{2}}\operatorname{S}\] is black

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  • question_answer20)                 Vapour pressure of pure benzene is 119 torr and that of toluene is 37.0 torr at the same temperature. Mole fraction of toluene in vapour phase which is equilibrium with a solution of benzene and toluene having a mole fraction of toluene 0.50 will be:     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                      0.137                  

    B)
                                             0.237

    C)
                                             0.435                  

    D)
                                             0.205

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  • question_answer21)                 In a face centred cubic lattice, atoms of A form the corner points and atoms of B form the face  points. If two atoms of A are missing form the corner points, the formula of the ionic compound is:     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                     \[{{\operatorname{AB}}_{3}}\]                                               

    B)
                                            \[{{\operatorname{AB}}_{4}}\]

    C)
                                            \[{{\operatorname{A}}_{2}}{{B}_{5}}\]                

    D)
                                            \[{{\operatorname{AB}}_{2}}\]

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  • question_answer22)                 The de Broglie wavelength of a car of mass 100 kg and velocity 36 km/hr is:                 \[(h=6.63\times {{10}^{-34}}\,Js)\]     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                     \[6.626\times {{10}^{-34}}\operatorname{m}\]               

    B)
                                            \[6.626\times {{10}^{-38}}\operatorname{m}\]

    C)
                                            \[6.626\times {{10}^{-31}}\operatorname{m}\]               

    D)
                                            \[6.626\times {{10}^{-30}}\operatorname{m}\]

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  • question_answer23)                 Given:                 \[E_{1/2/C{{l}_{2}}/c{{l}^{-}}}^{0}=1.36\,V,\,E_{C{{r}^{3+}}/Cr}^{0}=-0.74\,V\],                 \[E_{C{{r}_{2}}O_{7}^{2-}/C{{r}^{3+}}}^{0}=1.33\,V,\,E_{MnO_{4}^{-}/MnO_{{}}^{2+}}^{0}=1.51\,V\]                 The correct order of reducing power of the species \[(Cr,C{{r}^{3+}},M{{n}^{2+}}\text{and}\,\,C{{l}^{-}})\]be:     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                     \[M{{n}^{2+}}<C{{l}^{-}}<C{{r}^{3+}}<Cr\]

    B)
                                            \[M{{n}^{2+}}<C{{r}^{3}}^{-}<C{{l}^{-}}<Cr\]

    C)
                                            \[C{{r}^{3+}}<C{{l}^{-}}<M{{n}^{2+}}<Cr\]

    D)
                                            \[C{{r}^{3+}}<C{{l}^{-}}<Cr<M{{n}^{2}}^{+}\]

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  • question_answer24)                 Smoke is an example of:     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                      Solid disperse in solid

    B)
                                             Gas dispersed in liquid

    C)
                                             Solid dispersed in gas                   Smoke is an example of solid particles dispersed in gas.

    D)
                                             Gas dispersed in solid

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  • question_answer25)                 Which of the following statements/ relationships is not correct in thermodynamic changes?     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                      \[\Delta U=0\](isothermal reversible expansion of a gas)

    B)
                                             \[w=-nRT\ln \frac{{{V}_{2}}}{{{V}_{1}}}\](isothermal reversible expansion of an ideal gas)

    C)
                                             \[w=-nRT\ln \frac{{{V}_{2}}}{{{V}_{1}}}\](isothermal reversible expansion of an ideal gas)

    D)
                                             For a system of constant volume heat involved directly changes to internal energy.

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  • question_answer26)                 Bond distance in HF is \[9.17\times {{10}^{-11}}\operatorname{m}.\] Dipole moment of HF is \[6.104\times {{10}^{-30}}\operatorname{Cm}.\] The percent ionic character in HF will be (electron charge = \[6.104\times {{10}^{-19}}\operatorname{C}\])     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                      61.0 %

    B)
                                                             38.0%

    C)
                                             35.5 %                

    D)
                                             41.5 %

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  • question_answer27)                 The rate constant of a zero order reaction is \[2.0\times {{10}^{-2}}\]mol\[{{\operatorname{L}}^{-1}}\]\[{{\operatorname{s}}^{-1}}\]. If the concentration of the reactant after 25 seconds is 0.5 M. What is the initial concentration?   JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                      0.5 M                  

    B)
                                             1.25 M

    C)
                                             12.5 M                               

    D)
                                             1.0 M

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  • question_answer28)                 Which of the following is the product of aldol condensation?     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                                     

    B)
                                            

    C)
                                            

    D)
                                            

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  • question_answer29)                 The order of amines in gaseous state is :     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                     \[{{1}^{0}}>{{2}^{0}}>{{3}^{0}}>\operatorname{N}{{\operatorname{H}}_{3}}\]

    B)
                                            \[{{3}^{0}}>{{2}^{0}}>\operatorname{N}{{\operatorname{H}}_{3}}>{{1}^{0}}\]

    C)
                                            

    D)
                                            \[{{\operatorname{NH}}_{3}}>{{1}^{0}}>{{2}^{0}}>{{3}^{0}}\]

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  • question_answer30)                 Monocarboxylic acids are functional isomers of:     JEE Main Online Paper ( Held On 23  April 2013 )

    A)
                      Ethers                                

    B)
                                             Amines

    C)
                                             Esters

    D)
                                             Alcohols

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Study Package

JEE Main Online Paper (Held On 23 April 2013)
 

   


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