JEE Main & Advanced JEE Main Paper (Held on 12-4-2019 Afternoon)

  • question_answer
    Thermal decomposition of a Mn compound (X) at 513 K results in compound \[Y,Mn{{O}_{2}}\]and a gaseous product. \[Mn{{O}_{2}}\] reacts with NaCl and concentrated \[{{H}_{2}}S{{O}_{4}}\] to give a pungent gas Z. X, Y and Z, respectively. [JEE Main 12-4-2019 Afternoon]

    A) \[{{K}_{2}}Mn{{O}_{4}},KMn{{O}_{4}}\text{and}\,S{{O}_{2}}\]

    B) \[{{K}_{2}}Mn{{O}_{4}},KMn{{O}_{4}}\text{and}\,C{{l}_{2}}\]

    C) \[{{K}_{3}}Mn{{O}_{4}},KMn{{O}_{4}}\text{and}\,C{{l}_{2}}\]

    D) \[KMn{{O}_{4}},{{K}_{2}}Mn{{O}_{4}}\,\text{and}\,C{{l}_{2}}\]

    Correct Answer: D

    Solution :

    \[\underset{(X)}{\mathop{2KMn{{O}_{4}}}}\,\xrightarrow[\Delta ]{513K}\underset{(Y)}{\mathop{{{K}_{2}}Mn{{O}_{4}}}}\,+Mn{{O}_{2}}+{{O}_{2(g)}}\]       \[Mn{{O}_{2}}+4NaCl+4{{H}_{2}}S{{O}_{4}}\to MnC{{l}_{2}}+4NaHS{{O}_{4}}\]           \[+2{{H}_{2}}O+C{{l}_{2(g)}}(Z)\]pungent gas


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