JEE Main & Advanced JEE Main Online Paper (Held On 23 April 2013)

  • question_answer
                    The order of reactivity of the given haloalkanes towards nuclephlile is:     JEE Main Online Paper ( Held On 23  April 2013 )

    A)                  \[R\,I<R\,Br<R\,Cl\]      

    B)                                         \[R\,\,Cl>R\,\,Br>R\,\,I\]

    C)                                         \[R\,\,Br>R\,\,Cl>R\,\,I\]            

    D)                                         \[R\,\,Br>R\,\,I\,\,>\,R\,\,Cl\]

    Correct Answer: A

    Solution :

                      For a given alkyl group, the order of reactivity is . \[\frac{R-I>R-Br>R-Cl>R-F}{\text{increasing}\,\text{bond}\,\text{energy}}\] decreasing halogen reactivity. This order depends on the carbon-halogen  bond energy; the carbon-fluorine bond energy is maximum and thus fluorides are least reactive while carbon-iodine bond energy is minimum hence iodides are most reactive.


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