JEE Main & Advanced JEE Main Paper (Held On 09-Jan-2019 Morning)

  • question_answer
    Two complexes \[\left[ Cr{{\left( {{H}_{2}}0 \right)}_{6}} \right]C{{l}_{3}}\] and \[\left[ Cr{{\left( N{{H}_{3}} \right)}_{6}} \right]C{{l}_{3}}\] are violet and yellow coloured, respectively. The  incorrect statement regarding, them is- [JEE Main Online Paper (Held On 09-Jan-2019 Morning]

    A) \[{{\Delta }_{0}}\] value for is less than that of (B).

    B) both absorb energies corresponding to their complementary colors.

    C) \[{{\Delta }_{0}}\] values of and are calculated. From the energies of violet and yellow light, respectively.

    D) both are paramagnetic with three unpaired electrons.

    Correct Answer: C

    Solution :

    \[{{\Delta }_{0}}\] order will be compared by spectro- chemical series not by energies of violet and yellow light so \[{{\Delta }_{0}}\] order is \[\left[ Cr{{\left( {{H}_{2}}O \right)}_{6}}]C{{l}_{3}}<\text{ } \right[Cr{{\left( N{{H}_{3}} \right)}_{6}}]C{{l}_{3}}\]


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