JEE Main & Advanced JEE Main Paper (Held On 11-Jan-2019 Evening)

  • question_answer
    For the equilibrium,\[2{{H}_{2}}O{{H}_{3}}{{O}^{+}}+O{{H}^{-}},\]the value of \[\Delta {{G}^{o}}\]at 298 K is approximately [JEE  Main Online Paper (Held on 11-jan-2019 Evening)]

    A) \[-80kJ\,mo{{l}^{-1}}\]                        

    B) \[100kJ\,mo{{l}^{-1}}\]

    C) \[-100kJ\,mo{{l}^{-1}}\]                      

    D)   \[80kJ\,mo{{l}^{-1}}\]

    Correct Answer: D

    Solution :

    \[2{{H}_{2}}O\rightleftharpoons {{H}_{3}}{{O}^{+}}+O{{H}^{-}}\] \[{{K}_{w}}={{10}^{-14}}\] \[\Delta {{G}^{o}}=-2.303RT\log \,K\] \[=-2.303\,RT\log {{10}^{-14}}\] \[=+2.303\times 8.314\times 298\times 14=80kJ\,mo{{l}^{-1}}\]


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