JEE Main & Advanced JEE Main Paper Phase-I (Held on 08-1-2020 Morning)

  • question_answer
    As per Hardy-Schulze formulation, the flocculation values of the following for ferric hydroxide sol are in the order [JEE MAIN Held On 08-01-2020 Morning]

    A) \[AlC{{l}_{3}}>{{K}_{3}}\left[ Fe{{\left( CN \right)}_{6}} \right]>{{K}_{2}}Cr{{O}_{4}}>KBr=KN{{O}_{3}}\]

    B) \[{{K}_{3}}\left[ Fe{{\left( CN \right)}_{6}} \right]<{{K}_{2}}Cr{{O}_{4}}<KBr=KN{{O}_{3}}=AlC{{l}_{3}}\]

    C) \[{{K}_{3}}\left[ Fe{{\left( CN \right)}_{6}} \right]>AlC{{l}_{3}}>{{K}_{2}}Cr{{O}_{4}}>KBr>KN{{O}_{3}}\]

    D) \[{{K}_{3}}\left[ Fe{{\left( CN \right)}_{6}} \right]<{{K}_{2}}Cr{{O}_{4}}<AlC{{l}_{3}}<KBr<KN{{O}_{3}}\]

    Correct Answer: B

    Solution :

    [b] \[Fe{{\left( OH \right)}_{3}}\]is a positive sol. Its coagulation will be caused by the anion of the electrolyte. The flocculation value is inversely proportional to coagulation power or valence of the anion. The correct order of flocculation value is \[{{K}_{3}}\left[ Fe{{\left( CN \right)}_{6}} \right]<{{K}_{2}}Cr{{O}_{4}}<KBr=KN{{O}_{3}}=AlC{{l}_{3}}\]


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