A) sulphuryl chloride \[(S{{O}_{2}}C{{l}_{2}})\]
B) \[PC{{l}_{5}}\]
C) \[{{H}_{3}}P{{O}_{3}}\]
D) none of the above
Correct Answer: A
Solution :
Sulphuric acid reacts with \[PC{{l}_{5}}\], to give sulphuryl chloride\[(S{{O}_{2}}C{{l}_{2}})\]and phosphorus oxy-trichloride\[(POC{{l}_{3}}).\] \[{{H}_{2}}S{{O}_{4}}+2PC{{l}_{5}}\xrightarrow{{}}S{{O}_{2}}C{{l}_{2}}+2POC{{l}_{3}}+2HCl\]
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