JIPMER Jipmer Medical Solved Paper-2005

  • question_answer
    Butyne-1   and   butyne-2   can   be distinguished by:

    A)  \[{{H}_{2}}S{{O}_{4}}\]                

    B)  \[AgN{{O}_{3}}+N{{H}_{4}}OH\]             

    C)  \[{{K}_{2}}C{{r}_{2}}{{O}_{7}}\]

    D)         \[N{{H}_{4}}OH\]

    Correct Answer: B

    Solution :

    Butyne-1, has the terminal hydrogen atom which reacts with ammonical silver nitrate easily and liberate hydrogen. \[2C{{H}_{3}}C{{H}_{2}}C\equiv CH+A{{g}_{2}}O\xrightarrow{{}}\]                                            \[\underset{white\,ppt}{\mathop{C{{H}_{3}}C{{H}_{2}}C\equiv CAg+{{H}_{2}}O}}\,\] Hence butyne-1 and butyne-2 are distinguished by\[AgN{{O}_{3}}+N{{H}_{4}}OH\]


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