JIPMER Jipmer Medical Solved Paper-2009

  • question_answer
    The reaction, \[{{C}_{6}}{{H}_{5}}CHO+C{{H}_{3}}COO{{C}_{2}}{{H}_{5}}\xrightarrow{{}}\]\[{{C}_{6}}{{H}_{5}}CH=CHCOO{{C}_{2}}{{H}_{5}}\] is called

    A)  Benzoin condensation

    B)  Claisen condensation

    C)  Cahnizaros reaction

    D)  Perkin reaction

    Correct Answer: B

    Solution :

    Claisen condensation: Aromatic aldehyde condenses with esters having \[\alpha \text{-}\]hydrogen atoms like ethyl acetate, in the presence of metallic Na and \[{{C}_{2}}{{H}_{5}}OH\] to form esters of \[\alpha ,\]  \[\beta \text{-}\]unsaturated acids. \[\underset{benzaldehyde}{\mathop{{{C}_{6}}{{H}_{5}}CHO\,}}\,+\underset{ethyl\,\,acetate}{\mathop{{{H}_{2}}CH-COO{{C}_{2}}{{H}_{5}}}}\,\xrightarrow[{{C}_{2}}{{H}_{5}}OH]{Na}\]        \[\underset{ehtyl\,\,cinnamate}{\mathop{{{C}_{6}}{{H}_{5}}CH=CHCOO{{C}_{2}}{{H}_{5}}}}\,+{{H}_{2}}O\]


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