JIPMER Jipmer Medical Solved Paper-2013

  • question_answer
    On addition of small amount of\[KMn{{O}_{4}}\]to cone. \[{{H}_{2}}S{{O}_{4}},\] a green oily compound is obtained which is highly explosive in nature. Identify the compound from the following.

    A)  \[M{{n}_{2}}{{O}_{7}}\]

    B)                         \[Mn{{O}_{2}}\]             

    C)         \[MnS{{O}_{4}}\]           

    D)         \[M{{n}_{2}}{{O}_{3}}\]

    Correct Answer: A

    Solution :

    When \[KMn{{O}_{4}}\] react with \[{{H}_{2}}S{{O}_{4}}\] (cone.) we get a highly explosive compound\[M{{n}_{2}}{{O}_{7}}\]. The following reaction take place. \[KMn{{O}_{4}}+{{H}_{2}}S{{O}_{4}}(conc.)\to \] \[\underset{\text{Green}\,\,\text{oily}}{\mathop{M{{n}_{2}}{{O}_{7}}}}\,+2KHS{{O}_{4}}+{{H}_{2}}O\]


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