JIPMER Jipmer Medical Solved Paper-2013

  • question_answer
    During estimation of nitrogen in the organic compound by Kjeldahl?s method, the ammonia evolved from 0.5 g of the compound in Kjeldahl?s estimation of nitrogen, neutralized 10 mL of 1M\[{{H}_{2}}S{{O}_{4}}.\] Find out the percentage of nitrogen in the compound.

    A)  14%          

    B)                        28%                      

    C)  56%                      

    D)         68%

    Correct Answer: C

    Solution :

    \[1\,M\]or \[10\,mL\]\[{{H}_{2}}S{{O}_{4}}=1M\]of \[20\,mL\,N{{H}_{3}}\] 1000 mL of 1 M ammonia contains = 14 g nitrogen 20 mL of \[1\,M\,N{{H}_{3}}\] contains \[=\frac{14\times 20}{1000}g\]nitrogen % age of nitrogen                 \[=\frac{14\times 20\times 100}{1000\times 0.5}=56.0\,%\]


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