Manipal Engineering Manipal Engineering Solved Paper-2012

  • question_answer
    Complete the following reaction,                 \[{{P}_{4}}+NaOH+{{H}_{2}}O\xrightarrow{{}}?\]

    A) \[P{{H}_{3}}+N{{a}_{2}}HP{{O}_{2}}\]

    B) \[P{{H}_{3}}+Na{{H}_{2}}P{{O}_{2}}\]

    C) \[{{H}_{3}}P{{O}_{4}}+NaO\]     

    D) \[P{{H}_{3}}+N{{a}_{2}}P{{O}_{4}}\]

    Correct Answer: B

    Solution :

    \[\underset{\begin{smallmatrix}  White \\  phosphorus \end{smallmatrix}}{\mathop{{{P}_{4}}}}\,+3NaOH+3{{H}_{2}}O\xrightarrow{\Delta }\underset{Phosphene}{\mathop{P{{H}_{3}}}}\,\]                                                         \[+\underset{Sodium\,\,hypophosphate}{\mathop{3Na{{H}_{2}}P{{O}_{2}}}}\,\]


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