Manipal Engineering Manipal Engineering Solved Paper-2012

  • question_answer
    The oxidation number of sulphur in\[{{H}_{2}}{{S}_{2}}{{O}_{8}}\]is

    A) +2                                          

    B) +4

    C) +6                          

    D)        +7

    Correct Answer: C

    Solution :

    \[H-O-\underset{\begin{smallmatrix}  | \\  O \end{smallmatrix}}{\overset{\begin{smallmatrix}  O \\  || \end{smallmatrix}}{\mathop{S}}}\,-O-O-\underset{\begin{smallmatrix}  | \\  O \end{smallmatrix}}{\overset{\begin{smallmatrix}  O \\  || \end{smallmatrix}}{\mathop{S}}}\,-O-H\]                                                                                                            \[\because \]\[2O-\]atoms are in peroxide linkage \[\therefore \] Their oxidation state\[=-1\] and, oxidation state of remaining \[6O-\]atoms\[=-2\] Oxidation state of H-atoms\[=+1\] Let oxidation state of S atom\[=x\]                 \[{{S}_{2}}\]       \[{{H}_{2}}\]       \[{{O}_{6}}\]      \[{{O}_{2}}\] \[\therefore \]  \[2x+2(+1)+6(-2)+2(-1)=0\]                         \[2x+2-12-2=0\] \[x=x+6\]


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