Manipal Medical Manipal Medical Solved Paper-2004

  • question_answer
    The\[BC{{l}_{3}}\]is a planar molecule whereas\[NC{{l}_{3}}\]is pyramidal, because:

    A)  nitrogen atom is smaller than boron atoms

    B) \[B-Cl\]bond is more polar than\[N-Cl\]bond.

    C) \[N-Cl\]bond is more covalent than \[B-Cl\] bond

    D) \[BC{{l}_{3}}\]has no lone pair but\[NC{{l}_{3}}\]has a lone pair of electrons

    Correct Answer: D

    Solution :

     In boron trichloride, boron is\[s{{p}^{2}}\]hybridised and there is no lone pair on boron while in nitrogen. It is\[s{{p}^{3}}\] hybridised and there is a lone pair of electron in nitrogen. Hence, due to this reson\[BC{{l}_{3}}\]is a planer molecule and\[NC{{l}_{3}}\]is a pyramidal molecule.


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