Manipal Medical Manipal Medical Solved Paper-2008

  • question_answer
    Which of the following salt would give\[S{{O}_{2}}\] with hot and dil.\[{{H}_{2}}S{{O}_{4}}\]and also decolourises\[B{{r}_{2}}\]water?

    A)  \[N{{a}_{2}}S{{O}_{3}}\]        

    B)  \[NaHS{{O}_{4}}\]

    C)  \[N{{a}_{2}}S{{O}_{4}}\]        

    D)  \[N{{a}_{2}}S\]

    Correct Answer: A

    Solution :

     \[N{{a}_{2}}S{{O}_{3}}\]reacts with hot and dil.\[{{H}_{2}}S{{O}_{4}}\]to give \[S{{O}_{2}}\]gas which decolourise bromine water \[N{{a}_{2}}S{{O}_{3}}+{{H}_{2}}S{{O}_{4}}\xrightarrow[{}]{{}}N{{a}_{2}}S{{O}_{4}}+S{{O}_{2}}+{{H}_{2}}O\] \[B{{r}_{2}}+{{H}_{2}}O\xrightarrow[{}]{{}}2HBr+[O]\] \[S{{O}_{2}}+[O]\xrightarrow[{}]{{}}S{{O}_{3}}\] decolourisation of bromine water.


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