NEET Chemistry NEET PYQ-Chemical Kinetics

  • question_answer
    For the reaction \[2A+B~\to 3C+D\]which of the following does not express the reaction rate?  [AIPMT (S) 2006]

    A) \[-\frac{d\,[C]}{3\,dt}\]

    B) \[-\frac{d\,[B]}{dt}\]      

    C) \[\frac{d\,[D]}{dt}\]

    D)  \[-\frac{d\,[A]}{2\,dt}\]

    Correct Answer: A

    Solution :

    [a] For the reaction 2A + B \[\to \] 3C + D
                The reaction rate is written as follows:
                The reaction rate w.r.t. \[A=-\frac{1}{2}\,\frac{d\,[A]}{dt}\]
                The reaction rate w.r.t \[B=-\frac{d\,[B]}{dt}\]
                The reaction rate w.r.t \[C=+\frac{1}{3}\,\frac{d\,[C]}{dt}\]
                The reaction rate w.r.t \[D=\frac{d\,[D]}{dt}\] for product we take + sign because concentration of product increases with time
                Hence, the answer is not correct expression to represent the rate of reaction.


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