NEET Chemistry NEET PYQ-Solutions

  • question_answer
    1.00 g of a non-electrolyte solute (molar mass\[250g\text{ }mo{{l}^{-1}}\]) was dissolved in 51.2 g of benzene. If the freezing point depression constant, \[{{K}_{f}}\] of benzene is \[5.12\text{ }K\text{ }kg\text{ }mo{{l}^{-1}},\] the freezing point of benzene will be lowered by:   [AIPMT (S) 2006]

    A) 0.4 K

    B) 0.3 K

    C) 0.5 K

    D) 0.2 K

    Correct Answer: A

    Solution :

    [a] Molality of non-electrolyte solute
                \[=\frac{\frac{weight\,of\,solute\,in\,gram}{molecular\,weight\,of\,solute}}{weight\,of\,solvent\,in\,kg}\]
                \[=\frac{\frac{1}{250}}{0.0512}=\frac{1}{250\times 0.0512}=0.0781\,m\]
                \[\Delta {{T}_{f}}={{k}_{f}}\times molality\,of\,solution\]
                \[=5.12\times 0.0781=0.4\,K\]


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