question_answer 1) How many gram of dibasic acid (mol. wt. 200) should be present in 100 mL of the aqueous solution to give 0.1 N? [AIPMT 1999]
A)
1 g
done
clear
B)
2 g
done
clear
C)
10 g
done
clear
D)
20 g
done
clear
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question_answer 2) The strongest conjugate base is: [AIPMT 1999]
A)
\[NO_{3}^{-}\]
done
clear
B)
\[C{{l}^{-}}\]
done
clear
C)
\[SO_{4}^{2-}\]
done
clear
D)
\[C{{H}_{3}}CO{{O}^{-}}\]
done
clear
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question_answer 3) The conjugate acid of \[NH_{2}^{-}\] is: [AIPMT 2000]
A)
\[{{N}_{2}}{{H}_{4}}\]
done
clear
B)
\[NH_{4}^{+}\]
done
clear
C)
\[N{{H}_{2}}OH\]
done
clear
D)
\[N{{H}_{3}}\]
done
clear
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question_answer 4) In \[H{{S}^{-}},\,\,{{I}^{-}},\,\,RN{{H}_{2}},\,\,N{{H}_{3}}\] order of proton accepting tendency will be: [AIPMT 2001]
A)
\[{{I}^{-}}>N{{H}_{3}}>RN{{H}_{2}}>H{{S}^{-}}\]
done
clear
B)
\[N{{H}_{3}}>RN{{H}_{2}}>H{{S}^{-}}>{{I}^{-}}\]
done
clear
C)
\[RN{{H}_{2}}>N{{H}_{3}}>H{{S}^{-}}>{{I}^{-}}\]
done
clear
D)
\[H{{S}^{-}}>RN{{H}_{2}}>N{{H}_{3}}>{{I}^{-}}\]
done
clear
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question_answer 5) Which of the following order is wrong? [AIPMT 2002]
A)
\[N{{H}_{3}}<\text{ }P{{H}_{3}}<\text{ }As{{H}_{3}}\]acidic
done
clear
B)
\[Li<Be<B<C-\]1st IP
done
clear
C)
\[A{{I}_{2}}{{O}_{3}}<MgO<N{{a}_{2}}O<{{K}_{2}}O\]basic
done
clear
D)
\[L{{i}^{+}}<N{{a}^{+}}<{{K}^{+}}<C{{s}^{+}}-\]ionic radius
done
clear
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question_answer 6) Which one of the following orders of acid strength is correct? [AIPMT 2003]
A)
\[RCOOH>HOH>HC~CH>ROH\]
done
clear
B)
\[RCOOH>HC~CH>HOH>ROH\]
done
clear
C)
\[RCOOH>ROH>HOH>HC~CH\]
done
clear
D)
\[RCOOH>HOH>ROH>HC~CH\]
done
clear
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question_answer 7) Which is the best description of behaviour of bromine in the reaction given below\[{{H}_{2}}O+B{{r}_{2}}\xrightarrow[{}]{{}}HBr+HOBr\] [AIPMT (S) 2004]
A)
Proton accepted only
done
clear
B)
Both oxidised and reduced
done
clear
C)
Oxidised only
done
clear
D)
Reduced only
done
clear
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question_answer 8) The correct order of acid strength is: [AIPMT (S) 2005]
A)
\[HClO<HCl{{O}_{2}}<HCl{{O}_{3}}<HCI{{O}_{4}}\]
done
clear
B)
\[HCl{{O}_{4}}<HClO<HCl{{O}_{2}}<HCl{{O}_{3}}\]
done
clear
C)
\[HCl{{O}_{2}}<HCl{{O}_{3}}<HCl{{O}_{4}}<HClO\]
done
clear
D)
\[HCl{{O}_{4}}<HCl{{O}_{3}}<HCl{{O}_{2}}<HClO\]
done
clear
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question_answer 9) Which of the following is not a correct statement? [AIPMT (S) 2006]
A)
The electron-deficient molecules can act as Lewis acids
done
clear
B)
The canonical structures have no real existence
done
clear
C)
Every AB5 molecule does in fact have square pyramid structure
done
clear
D)
Multiple bonds are always shorter than corresponding single bonds
done
clear
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question_answer 10) Which one of the following orders is not in accordance with the property stated against it? [AIPMT (S) 2006]
A)
\[{{F}_{2}}>C{{l}_{2}}>B{{r}_{2}}>{{I}_{2}}:\]Oxidising power
done
clear
B)
\[HI>HBr>HCI>HF:\]Acidic property in water
done
clear
C)
\[{{F}_{2}}>C{{l}_{2}}>B{{r}_{2}}>{{I}_{2}}:\]Electronegativity
done
clear
D)
\[{{F}_{2}}>C{{l}_{2}}>B{{r}_{2}}>{{I}_{2}}:\] Bond dissociation energy
done
clear
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question_answer 11) Which of die following represents the correct order of the acidity in the given compounds? [AIPMT (S) 2007]
A)
\[C{{H}_{3}}COOH>BrC{{H}_{2}}COOH>ClC{{H}_{2}}COOH\] \[>FC{{H}_{2}}COOH\]
done
clear
B)
\[FC{{H}_{2}}COOH>C{{H}_{3}}COOH>BrC{{H}_{2}}COOH\]\[>ClC{{H}_{2}}COOH\]
done
clear
C)
\[BrC{{H}_{2}}COOH>CIC{{H}_{2}}COOH>FC{{H}_{2}}COOH\]\[>C{{H}_{3}}COOH\]
done
clear
D)
\[FC{{H}_{2}}COOH>ClC{{H}_{2}}COOH>BrC{{H}_{2}}COOH\]\[>C{{H}_{3}}COOH\]
done
clear
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question_answer 12) Which one of the following ionic species has the greatest proton affinity to form stable compound? [AIPMT (S) 2007]
A)
\[H{{S}^{-}}\]
done
clear
B)
\[NH_{2}^{-}\]
done
clear
C)
\[{{F}^{-}}\]
done
clear
D)
\[{{I}^{-}}\]
done
clear
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question_answer 13) Which one of the following orders correctly represents the increasing acid strengths of the given acids? [AIPMT (S) 2007]
A)
\[HOCl<HOClO<HOCl{{O}_{2}}<HOCl{{O}_{3}}\]
done
clear
B)
\[HOClO<HOCl<HOCl{{O}_{3}}<HOCI{{O}_{2}}\]
done
clear
C)
\[HOCl{{O}_{2}}<HOCl{{O}_{3}}<HOClO<HOCl\]
done
clear
D)
\[HOCl{{O}_{3}}<HOCl{{O}_{2}}<HOClO<HOCl\]
done
clear
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question_answer 14)
Base strength of [AIPMT (S) 2008] (1) \[{{H}_{3}}C\overset{\Theta }{\mathop{C}}\,{{H}_{2}}\] (2) \[{{H}_{2}}C=\overset{\Theta }{\mathop{C}}\,H\]and (3) \[H-C\equiv \overset{\Theta }{\mathop{C}}\,\] is in the order of
A)
(2) > (1) > (3)
done
clear
B)
(3) > (2) > (1)
done
clear
C)
(1) > (3) > (2)
done
clear
D)
(1) > (2) > (3)
done
clear
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question_answer 15) Which of the following molecules acts as a Lewis acid? [AIPMT (S) 2009]
A)
\[{{(C{{H}_{3}})}_{3}}B\]
done
clear
B)
\[{{(C{{H}_{3}})}_{2}}O\]
done
clear
C)
\[{{(C{{H}_{3}})}_{2}}P\]
done
clear
D)
\[{{(C{{H}_{3}})}_{3}}N\]
done
clear
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question_answer 16) Which one of the following molecular hydrides acts as a Lewis acid? [AIPMT (S) 2010]
A)
\[N{{H}_{3}}\]
done
clear
B)
\[{{H}_{2}}O\]
done
clear
C)
\[{{B}_{2}}{{H}_{6}}\]
done
clear
D)
\[C{{H}_{4}}\]
done
clear
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question_answer 17) Which of the following is least likely to behave as Lewis base? [AIPMT (S) 2011]
A)
\[N{{H}_{3}}\]
done
clear
B)
\[B{{F}_{3}}\]
done
clear
C)
\[O{{H}^{-}}\]
done
clear
D)
\[{{H}_{2}}O\]
done
clear
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question_answer 18) The correct order of decreasing acid strength of trichloroacedc acid , trifluoroacetic acid, acetic acid and formic acid is [AIPMT (S) 2012]
A)
B > A > D > C
done
clear
B)
B > D > C > A
done
clear
C)
A > B > C > D
done
clear
D)
A > C > B > D
done
clear
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question_answer 19) In which of the following arrangements the given sequence is not strictly according to the property indicated against it? [AIPMT (M) 2012]
A)
\[HF<HCl<HBr,HI:\] increasing acidic strength
done
clear
B)
\[{{H}_{2}}O<{{H}_{2}}S<{{H}_{2}}Se<{{H}_{2}}Te:\] increasing \[p{{K}_{a}}\] values
done
clear
C)
\[N{{H}_{3}}<p{{H}_{3}}<As{{H}_{3}}<Sb{{H}_{3}}:\] increasing acidic character
done
clear
D)
\[C{{O}_{2}}<Si{{O}_{2}}<Sn{{O}_{2}}<Pb{{O}_{2}}\]: increasing oxidising power
done
clear
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question_answer 20) Which is the strongest acid in the following? [NEET 2013]
A)
\[{{H}_{2}}S{{O}_{4}}\]
done
clear
B)
\[HCl{{O}_{3}}\]
done
clear
C)
\[HCl{{O}_{4}}\]
done
clear
D)
\[{{H}_{2}}S{{O}_{3}}\]
done
clear
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question_answer 21) Which of these is least likely to act as a Lewis base? [NEET 2013]
A)
CO
done
clear
B)
\[{{F}^{-}}\]
done
clear
C)
\[B{{F}_{3}}\]
done
clear
D)
\[P{{F}_{3}}\]
done
clear
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question_answer 22) Acidity of diprotic acids in aqueous solutions increases in the order [AIPMT 2014]
A)
\[{{H}_{2}}S<{{H}_{2}}Se<{{H}_{2}}Te\]
done
clear
B)
\[{{H}_{2}}Se<{{H}_{2}}S<{{H}_{2}}Te\]
done
clear
C)
\[{{H}_{2}}Te<{{H}_{2}}S<{{H}_{2}}Se\]
done
clear
D)
\[{{H}_{2}}Se<{{H}_{2}}Te<{{H}_{2}}S\]
done
clear
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question_answer 23) Among the following, the correct order of acidity is [NEET - 2016]
A)
\[HCl{{O}_{3}}<HCl{{O}_{4}}<HCl{{O}_{2}}<HClO\]
done
clear
B)
\[~HClO<HCl{{O}_{2}}<HCl{{O}_{3}}<HCl{{O}_{4}}\]
done
clear
C)
\[HCl{{O}_{2}}<HClO<HCl{{O}_{3}}<HCl{{O}_{4}}\]
done
clear
D)
\[HCl{{O}_{4}}<HCl{{O}_{2}}<HClO<HCl{{O}_{3}}\]
done
clear
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question_answer 24) Which one is the correct order of acidity? [NEET-2017]
A)
\[C{{H}_{3}}=C{{H}_{3}}>C{{H}_{2}}=C{{H}_{2}}>C{{H}_{3}}-C\]\[=CH>CH=CH\]
done
clear
B)
\[C{{H}_{2}}=C{{H}_{2}}>C{{H}_{3}}-CH=C{{H}_{2}}>C{{H}_{3}}-C\]\[\equiv CH>CH\equiv CH\]
done
clear
C)
\[CH\equiv CH>C{{H}_{3}}-C\equiv CH>C{{H}_{2}}\]\[=C{{H}_{2}}>C{{H}_{3}}-C{{H}_{3}}\]
done
clear
D)
\[CH\equiv CH>C{{H}_{2}}=C{{H}_{2}}>C{{H}_{3}}-C\]\[\equiv CH>C{{H}_{3}}-C{{H}_{3}}\]
done
clear
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question_answer 25) Conjugate base for Bronsted acids \[{{H}_{2}}O\]and HF are: [NEET 2019]
A)
\[O{{H}^{}}\]and\[{{F}^{}}\], respectively
done
clear
B)
\[{{H}_{3}}{{O}^{+}}\]and\[{{H}_{2}}{{F}^{+}}\], respectively
done
clear
C)
\[O{{H}^{}}\]and\[{{H}_{2}}{{F}^{+}}\], respectively
done
clear
D)
\[{{H}_{3}}{{O}^{+}}\]and\[{{F}^{}}\], respectively
done
clear
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question_answer 26) Which will make basic buffer? [NEET 2019]
A)
\[100\text{ }mL\text{ }of\text{ }0.1\text{ }M\text{ }HCl+200\text{ }mL\text{ }of\text{ }\]\[0.1M\text{ }N{{H}_{4}}OH\]
done
clear
B)
\[100\text{ }mL\text{ }of\text{ }0.1\text{ }M\text{ }HCl+100\text{ }mL\text{ }of\text{ }\]\[0.1\text{ }M\text{ }NHOH\]
done
clear
C)
\[50\text{ }mL\text{ }of\text{ }0.1\text{ }M\text{ }NaOH+25\text{ }mL\text{ }of\]\[0.1\text{ }M\text{ }C{{H}_{3}}COOH\]
done
clear
D)
\[100\text{ }mL\text{ }of\text{ }0.1\text{ }M\text{ }C{{H}_{3}}COOH+100\]\[mL\text{ }of\text{ }0.1\text{ }M\text{ }NaOH\]
done
clear
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