question_answer15) Among the following series of transition metal ions, the one in which all metal ions have \[3{{d}^{2}}\]electronic configuration is: (At. no. :\[Ti=22;\]\[V=23;\]\[Cr=24;Mn=25\]) [AIPMT (S) 2004]
question_answer19) Four successive members of the first row transition elements are listed below with their atomic numbers. Which one of them is expected to have the highest third ionization enthalpy? [AIPMT (S) 2005]
question_answer20) The main reason for larger number of oxidation states exhibited by the actinides than the corresponding lanthanides, is: [AIPMT (S) 2005]
A)
lesser energy difference between 5 f and 6d orbitals than between 4f and 5d orbitals
doneclear
B)
larger atomic size of actinides than the lanthanides
doneclear
C)
more energy difference between 5f and 6d orbitals than between 4f and 5d orbitals
doneclear
D)
greater reactive nature of the actinides than the lanthanides
question_answer21) More number of oxidation states are exhibited by the actinoids than by the lanthanoids. The main reason for this is: [AIPMT (S) 2006]
A)
more energy difference between 5f and 6d orbitals than that between 4f and 5d orbitals
doneclear
B)
lesser energy difference between 5f and 6d orbitals than that between 4f and 5d orbitals
doneclear
C)
greater metallic character of the lanthanoids than that of the corresponding actinoids
question_answer27) Number of moles of \[MnO_{4}^{-}\] required to oxidize one mole of ferrous oxalate completely in acidic medium will be [AIPMT (S) 2008]
question_answer28) Which one of the elements with the following outer orbital configurations may exhibit the largest number of oxidation states? [AIPMT (S) 2009]
question_answer29) The ionisation constant of ammonium hydroxide is \[4\times {{10}^{-8}}m.\] at 298 K. Hydrolysis constant of ammonium chloride is [AIPMT (S) 2009]
question_answer30) Out of \[TiF_{6}^{2-},\,CoF_{6}^{3-},\,CuC{{l}_{2}}\] and \[NiCl_{4}^{2-}\] (Z of \[=k[A]{{[B]}^{2}}\]) the colourless species are [AIPMT (S) 2009]
A)
\[=k{{[A]}^{2}}{{[B]}^{2}}\]and \[=k[A][B]\]
doneclear
B)
\[N_{2}^{-}<{{N}_{2}}<N_{2}^{2-}\] and \[N_{2}^{2-}<N_{2}^{-}<{{N}_{2}}\]
For the four successive transition elements (Cr, Mn, Fe and Co), the stability of +2 oxidation state will be there in which of the following order? [AIPMT (S) 2011]
question_answer34) Acidified \[{{\text{K}}_{\text{2}}}\text{C}{{\text{r}}_{\text{2}}}{{\text{O}}_{\text{7}}}\] solution turns green when \[\text{N}{{\text{a}}_{\text{2}}}\text{S}{{\text{O}}_{\text{3}}}\]is added to it. This is due to the formation of [AIPMT (S) 2011]
question_answer35) In the extraction of copper from its sulphide ore, the metal is finally obtained by the reduction of cuprous oxide with [AIPMT (S) 2012]
question_answer36) Which of the statements is not true? [AIPMT (S) 2012]
A)
On passing \[{{\text{H}}_{\text{2}}}\text{S}\] through acidified \[{{\text{k}}_{\text{2}}}\text{C}{{\text{r}}_{\text{2}}}{{\text{O}}_{\text{7}}}\] solution, a milky colour is observed
doneclear
B)
\[\text{N}{{\text{a}}_{\text{2}}}\text{C}{{\text{r}}_{\text{2}}}{{\text{O}}_{\text{7}}}\]is preferred over \[{{\text{K}}_{\text{2}}}\text{C}{{\text{r}}_{\text{2}}}{{\text{O}}_{\text{7}}}\] in volumetric analysis
doneclear
C)
\[{{\text{K}}_{\text{2}}}\text{C}{{\text{r}}_{\text{2}}}{{\text{O}}_{\text{7}}}\] solution in acidic medium is orange
doneclear
D)
\[{{\text{K}}_{\text{2}}}\text{C}{{\text{r}}_{\text{2}}}{{\text{O}}_{\text{7}}}\] solution becomes yellow on increasing the pH beyond 7
question_answer38) Four successive members of the first series of the transition metals are listed below. For which one of them the standard potential \[({{E}^{o}}_{{{M}^{2+}}/M})\]positive sign? [AIPMT (M) 2012]
\[\text{KMn}{{\text{O}}_{\text{4}}}\] can be prepared from \[{{\text{K}}_{\text{2}}}\text{Mn}{{\text{O}}_{\text{4}}}\] as per reaction\[\text{3MnO}_{4}^{2-}+2{{H}_{2}}O2MnO_{4}^{-}\]\[+Mn{{O}_{2}}+4O{{H}^{-}}\][NEET 2013]
The reaction can go to completion by removing \[\text{O}{{\text{H}}^{\text{-}}}\] ions by adding
question_answer44) Because of lanthanoid contraction, which of the following pairs of elements have nearly same atomic radii? (Numbers in the parenthesis are atomic numbers). [NEET 2015 ]
question_answer45) Assuming complete ionisation, same moles of which of the following compounds will require the least amount of acidified \[KMn{{O}_{4}}\] for complete oxidation? [NEET 2015 (Re)]
question_answer46) Which one of the following statements is correct when \[\text{S}{{\text{O}}_{\text{2}}}\]is passed through acidified \[{{\text{K}}_{2}}C{{r}_{2}}{{O}_{7}}\]solution? [NEET - 2016]
question_answer52) Identify the incorrect statement. [NEET 2020]
A)
The transition metals and their compounds are known for their catalytic activity due to their ability to adopt multiple oxidation states and to form complexes.
doneclear
B)
Interstitial compounds are those that are formed when small atoms like H, C or N are trapped inside the crystal lattices of metals.
doneclear
C)
The oxidation states of chromium in \[CrO_{4}^{2-}\] and \[C{{r}_{2}}O_{4}^{2-}\] are not the same.
doneclear
D)
\[C{{r}^{2+}}({{d}^{4}})\] is a stronger reducing agent than \[F{{e}^{2+}}({{d}^{6}})\] in water.