RAJASTHAN ­ PET Rajasthan PET Solved Paper-2001

  • question_answer
    \[2C{{H}_{3}}-\underset{\begin{smallmatrix}  || \\  O \end{smallmatrix}}{\mathop{C}}\,-H\xrightarrow[{}]{Dil.base}X\xrightarrow[{}]{\Delta }Y\] Product ?Y? is

    A)  \[C{{H}_{3}}-CH=CH-\underset{\begin{smallmatrix}  || \\  O \end{smallmatrix}}{\mathop{C}}\,-H\]

    B)  \[C{{H}_{3}}-\underset{\begin{smallmatrix}  | \\  OH \end{smallmatrix}}{\mathop{CH}}\,-C{{H}_{2}}-\underset{\begin{smallmatrix}  || \\  O \end{smallmatrix}}{\mathop{C}}\,-H\]

    C)  \[C{{H}_{3}}-CH=CH-COOH\]

    D)  \[C{{H}_{3}}-\underset{\begin{smallmatrix}  | \\  OH \end{smallmatrix}}{\mathop{CH}}\,-C{{H}_{2}}-COOH\]

    Correct Answer: A

    Solution :

     \[\underset{acetaldehyde}{\mathop{\underset{\begin{smallmatrix}  || \\  O \end{smallmatrix}}{\mathop{C{{H}_{3}}CH}}\,}}\,+H.C{{H}_{2}}CHO\xrightarrow[{}]{Dil.\,base}\] \[\underset{(X)}{\mathop{C{{H}_{3}}-\underset{\begin{smallmatrix}  | \\  OH \end{smallmatrix}}{\mathop{CH}}\,-C{{H}_{2}}CHO}}\,\]       \[\xrightarrow[\Delta ]{-{{H}_{2}}O}\underset{(Y)}{\mathop{C{{H}_{3}}CH}}\,=CH-CHO\] This is aldol condensation reaction.


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