RAJASTHAN ­ PET Rajasthan PET Solved Paper-2004

  • question_answer
    Arrange the following acids in decreasing order of their\[p{{K}_{a}}\]values
    Formic acid (I)
    Acetic acid (II)
    Chloro acetic acid (III)
    Trichloro acetic acid (IV)

    A)  IV, III, II, I        

    B)  II, I, IV, III

    C)  II, I, III, IV        

    D)  I, II, IV, III

    Correct Answer: C

    Solution :

     The acidity increases on decreasing the value of\[p{{K}_{a}}\]. \[\underset{acetic\text{ }acid}{\mathop{C{{H}_{3}}COOH}}\,<\underset{formic\text{ }acid}{\mathop{HCOOH}}\,<\underset{chloroacetic\text{ }acid}{\mathop{ClC{{H}_{2}}COOH}}\,\] \[<\underset{\begin{smallmatrix}  trichloroacetic \\  \,\,\,\,\,\,\,\,\,\,\,acid \end{smallmatrix}}{\mathop{C{{l}_{3}}C.COOH}}\,\] \[\xrightarrow[Increasing\text{ }order\text{ }of\text{ }acidic\text{ }strength]{{}}\] or    Decreasing order of\[p{{K}_{a}}\].


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