RAJASTHAN ­ PET Rajasthan PET Solved Paper-2007

  • question_answer
    On isothermal expansion of ideal gas, its

    A)  internal energy increases

    B)  enthalpy increases

    C)  enthalpy becomes zero on decreasing

    D)  enthalpy remains unchanged

    Correct Answer: D

    Solution :

     Isothermal process \[dT=0,\] \[\Delta E=0\] \[H=E+pV\] \[\Delta H=\Delta E+p.\Delta V\] where, \[\Delta H=\] change in enthalpy \[\Delta E=\] change in internal energy \[p=\]pressure \[\Delta V=\]change in volume during expansion of ideal gas If \[pV=nRT\] \[\Delta H=\Delta E+\Delta (nRT)\] \[\Delta H=\Delta E+nR.\Delta T\] \[\Delta T=0\] \[\Delta E=0\](Isothermal expansion) Hence,    \[\Delta H=0\] During isothermal expansion, the enthalpy of ideal gas remains unchanged.


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