RAJASTHAN ­ PET Rajasthan PET Solved Paper-2009

  • question_answer
    An aqueous solution boils at\[100.2{}^\circ C\]. At which temperature this will freeze. \[({{K}_{b}}=0.5{}^\circ C/m,{{K}_{f}}=1.9{}^\circ C/m)\]

    A)  \[+0.76\]           

    B)  \[-0.76\]

    C)  \[-0.38\]            

    D)  \[+0.38\]

    Correct Answer: B

    Solution :

     \[\because \] \[{{T}_{b}}=100.2{}^\circ C\] \[\therefore \] \[\Delta {{T}_{b}}=100.2-100=0.2{}^\circ C\] \[\Delta {{T}_{b}}={{K}_{b}}\times m\] \[m=\frac{\Delta {{T}_{b}}}{{{K}_{b}}}=\frac{0.2}{0.5}=0.4\] \[\Delta {{T}_{f}}={{K}_{f}}\times m=1.9\times 0.4\] \[=0.76{}^\circ C\] \[\Delta {{T}_{f}}={{T}_{o}}-\Delta {{T}_{f}}=0-0.76\] \[=-0.76{}^\circ C\]


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