RAJASTHAN PMT Rajasthan - PMT Solved Paper-1995

  • question_answer
    If the concentration of \[Cr{{O}_{4}}^{---}\] in saturated solution of \[AgCr{{O}_{4}},\] then the solubility product is:

    A)  \[4\times {{10}^{-8}}\]

    B)  \[8\times {{10}^{-12}}\]

    C)  \[16\times {{10}^{-12}}\]

    D)  \[32\times {{10}^{-12}}\]

    Correct Answer: D

    Solution :

    In saturated solution of silver chromate. \[AgCr{{O}_{4}}\xrightarrow{{}}\underset{\begin{smallmatrix}  2\times 2\times {{10}^{-2}}m \\  =4\times {{10}^{-4}}m \end{smallmatrix}}{\mathop{2A{{g}^{+}}}}\,+\underset{2\times {{10}^{-4}}m}{\mathop{Cr{{O}_{4}}^{-\,\,-}}}\,\] (according to questions) \[AgCr{{O}_{4}}[Ksp]={{[A{{g}^{+}}]}^{2}}\times [Cr{{O}_{4}}^{-\,\,-}]\]                                 \[={{[4\times {{10}^{-4}}]}^{2}}\times [2\times {{10}^{-4}}]\]                                 \[=32\times {{10}^{-12}}\]


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