RAJASTHAN PMT Rajasthan - PMT Solved Paper-2002

  • question_answer
    At \[298\text{ }K,\] the solubility of \[PbC{{l}_{2}}\]is \[2\times {{10}^{-2}}\text{ }mol/litre\]then \[{{K}_{sp}}=?\]:

    A)  \[1\times {{10}^{-7}}\]

    B)  \[3.2\times {{10}^{-2}}\]

    C)  \[1\times {{10}^{-5}}\]         

    D)  \[3.2\times {{10}^{-5}}\]

    Correct Answer: D

    Solution :

    Given, solubility of \[PbC{{l}_{2}}(s)=2\times {{10}^{-2}}mol/litre\]                 \[PbC{{l}_{2}}Pb+2C{{l}^{-}}\]                 \[{{K}_{sp}}=[s]\,{{[2s]}^{2}}\]                 \[=4{{s}^{3}}\]                 \[=4\times {{(2\times {{10}^{-2}})}^{3}}\]                 \[=32\times {{10}^{-6}}\]                 \[{{K}_{sp}}=3.2\times {{10}^{-5}}\]


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