RAJASTHAN PMT Rajasthan - PMT Solved Paper-2003

  • question_answer
    Chloroform reacts with cone. \[HN{{O}_{3}}\]to give

    A)  \[CHC{{l}_{2}}N{{O}_{2}}\]

    B)         \[CHC{{l}_{2}}N{{O}_{3}}\]

    C)         \[CC{{l}_{3}}N{{O}_{2}}\]

    D)         \[CHC{{l}_{2}}.HN{{O}_{3}}\]

    Correct Answer: C

    Solution :

    \[\underset{chloroform}{\mathop{CHC{{l}_{3}}}}\,+HN{{O}_{3}}\xrightarrow{{}}\underset{chloropicrin}{\mathop{CC{{l}_{3}}N{{O}_{2}}}}\,\] Thus chloroform reacts with con. \[HN{{O}_{3}}\] to produce \[CC{{l}_{3}}.N{{O}_{2}}\].


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