RAJASTHAN PMT Rajasthan - PMT Solved Paper-2005

  • question_answer
    \[35.4\,\,mL\] of \[HO\] is required for the neutralization of a solution containing 0.275 g of sodium hydroxide. The normality of hydrochloric acid is?

    A) \[0.97\,\,N\]                               

    B) \[0.142\,\,N\]

    C) \[0.194\,\,N\]   

    D)        \[0.244\,\,N\]

    Correct Answer: C

    Solution :

    We know that \[1\,\,g\] equivalent weight of \[NaOH=40\,\,g\] \[\therefore \]\[40\,\,g\]of \[NaOH=1\,\,g\]eq. of\[NaOH\] \[\therefore \]\[0.275\,\,g\] of\[NaOH=\frac{1}{40}\times 0.275\,\,eq\].                 \[=\frac{1}{40}\times 0.275\times 1000\]                 \[=6.88\,\,meq\] \[\because \]           \[\underset{(HCl)}{\mathop{{{N}_{1}}{{V}_{1}}}}\,=\underset{(NaOH)}{\mathop{{{N}_{2}}{{V}_{2}}}}\,\]                 \[{{N}_{1}}\times 35.4=6.88\]         \[(\because \,\,meq=NV)\] \[\therefore \]                            \[{{N}_{1}}=0.194\]


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