RAJASTHAN PMT Rajasthan - PMT Solved Paper-2007

  • question_answer
    Glucose reacts with excess of phenyl hydrazine and forms

    A)  glucosazone

    B)        glucose phenyl hydrazine

    C)        glucose oxime

    D)        sorbitol

    Correct Answer: A

    Solution :

    Glucose react with 3 molecules of phenyl hydrazine and form glucosazone. \[\underset{\begin{align}   & | \\  & CHOH \\  & | \\  & {{(CHOH)}_{3}}+3{{C}_{6}}{{H}_{5}}NH\cdot N{{H}_{2}}\xrightarrow{{}} \\  & | \\  & C{{H}_{2}}OH \\  & \text{glucose} \\ \end{align}}{\mathop{CHO}}\,\]                                                      \[\underset{\begin{align}   & | \\  & C=N\cdot NH{{C}_{6}}{{H}_{5}} \\  & | \\  & {{(CHOH)}_{3}} \\  & | \\  & C{{H}_{2}}OH \\  & \text{glucosazone} \\ \end{align}}{\mathop{C}}\,H=N\cdot NH{{C}_{6}}{{H}_{5}}\]


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