Uttarakhand PMT Uttarakhand PMT Solved Paper-2010

  • question_answer
    Which of the following is applied in this reaction? \[C{{H}_{3}}CHBrC{{H}_{2}}C{{H}_{3}}\xrightarrow[{}]{Alc.\,KOH}\] (i) \[C{{H}_{3}}CH=CHC{{H}_{3}}\]major product (ii)\[C{{H}_{2}}=CHC{{H}_{2}}C{{H}_{3}}\]minor product

    A)  Hermanns rule  

    B)  Kharasch effect

    C)  Saytzeffs rule   

    D)  Markownikoffs rule

    Correct Answer: C

    Solution :

     \[C{{H}_{3}}-\underset{\begin{smallmatrix}  | \\  Br \end{smallmatrix}}{\mathop{CH}}\,-C{{H}_{2}}C{{H}_{3}}\xrightarrow[{}]{Alc.KOH}\] \[\underset{(major\text{ }product)}{\mathop{C{{H}_{3}}CH=CHC{{H}_{3}}}}\,+\underset{(minor\text{ }product)}{\mathop{C{{H}_{2}}=CHC{{H}_{2}}C{{H}_{3}}}}\,\] The elimination takes place according to Saytzeffs rule which states that more substituent alkene is the major products.


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