WB JEE Medical WB JEE Medical Solved Paper-2013

  • question_answer
    Which of the following lanthanide ions is diamagnetic? \[(At\,nos.\,Ce=58,\,Sm=62,\,Eu=63,\,Yb=70)\]

    A)  \[C{{e}^{2+}}\]

    B)  \[S{{m}^{2+}}\]

    C)  \[E{{u}^{2+}}\]

    D)  \[Y{{b}^{2+}}\]

    Correct Answer: D

    Solution :

     Lanthanoid ion with no unpaired electron is diamagnetic in nature. \[C{{e}_{58}}=[Xe]4{{f}^{2}}5{{d}^{0}}6{{s}^{2}}\] \[C{{e}^{2+}}=[Xe]4{{f}^{2}}\](Two unpaired electrons! \[S{{m}_{62}}=[Xe]4{{f}^{6}}5{{d}^{0}}6{{s}^{2}}\] \[S{{m}^{2+}}=[Xe]4{{f}^{6}}\](Six unpaired electrons) \[E{{u}_{63}}[Xe]4{{f}^{7}}5{{d}^{0}}6{{s}^{2}}\] \[E{{u}^{2+}}=[Xe]4{{f}^{7}}\](Seven unpaired electrons) \[Y{{b}_{70}}=[Xe]4{{f}^{14}}5{{d}^{0}}6{{s}^{2}}\] \[Y{{b}^{2+}}=[Xe]4{{f}^{14}}\](No unpaired electrons) Because of the absence of unpaired electrons, \[Y{{b}^{2+}}\]is diamagnetic.


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