WB JEE Medical WB JEE Medical Solved Paper-2014

  • question_answer
    The most likely protonation site in the following molecule is

    A)  \[C-1\]

    B)  \[C-2\]

    C) \[C-3\]

    D)  \[C-4\]

    Correct Answer: A

    Solution :

     Addition of a proton at \[{{C}^{1}}\]results in the formation of tropylium carbocation (an aromatic species with more stability due to delocalization of n electrons), thus, it is the most reactive site towards protonation. Addition of proton at any other carbon atom, interupt in the delocalisation of \[\pi \]electrons by disturbing planarity of molecules and hence, makes it less stable. Thus, these all are less reactive towards protonation.


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