12th Class Chemistry The p-block Elements-II / p-ब्लॉक तत्व-II Question Bank 11th CBSE Chemistry The P-Block Elements

  • question_answer
    Why carbon forms covalent compounds whereas lead forms ionic compounds?

    Answer:

                    Carbon cannot lose all the four valence electrons to form \[{{C}^{4+}}\] ions because the sum of the first four ionization enthalpies of carbon is very large. It also cannot gain four electrons to form \[{{C}^{4-}}\]ion as this anion would be highly unstable because it would be very difficult for a nucleus with only 6 protons to hold on firmly 10 electrons. Therefore, carbon forms only covalent compounds by sharing of electrons : In contrast, due to inert pair effect, + 2 oxidation state of Pb is more stable than its +4 oxidation state. Further, on moving down the group, the ionization enthalpy decreases. As a result, the sum of the first two ionization enthalpies of Pb is quite low and hence Pb can easily lose two electrons to form \[P{{b}^{2+}}\] ions. Consequently, Pb forms ionic compounds.


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