12th Class Chemistry Biomolecules / जैव-अणु Question Bank 12th CBSE Chemistry Biomolecules

  • question_answer
    Can the acid chloride of an \[\alpha \]-amino acid be made by treating it with \[SOC{{l}_{2}}\]?

    Answer:

                    No. Two molecules of the initially formed\[\alpha \]-amino acid chloride react with each other to form a dipeptide acid chloride which, in turn, reacts further to form tetrapeptide acid chloride, etc.                 \[N{{H}_{2}}-CHR-COOH+SOC{{l}_{2}}\xrightarrow{\,}\]\[N{{H}_{2}}-CHR-COCl+S{{O}_{2}}+HCl\]                 \[\underset{\begin{smallmatrix}                  \text{ }\!\!\alpha\!\!\text{ -Amino}\,\,\text{acid}\,\text{chloride} \\                 \,\,\,\,\,\,\text{(two}\,\text{molecules)}                 \end{smallmatrix}}{\mathop{N{{H}_{2}}CHRCOCl+N{{H}_{2}}CHRCOCl}}\,\]\[\xrightarrow{-HCl}\underset{\text{Dipeptide}\,\,\text{acid}\,\,\text{chloride}}{\mathop{N{{H}_{2}}CHRCONHCHRCOCl}}\,\]\[\xrightarrow{}\xrightarrow{}\xrightarrow{}\,\,etc.\]


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