Answer:
When \[CdC{{l}_{2}}\]is added to the
crystals of \[AgCl,\] the replacement of one \[A{{g}^{+}}\] ion with \[C{{d}^{2+}}\]
ion necessitates the removal of second \[A{{g}^{+}}\] ion from the lattice to
maintain the electrical neutrality of the crystal. However, the same does not
take place in case of NaCI because both \[A{{g}^{+}}\] and\[N{{a}^{+}}\] ions
are monovalent. Thus, Schottky defects are caused by the addition of \[CdC{{l}_{2}}\]and
not by NaCI.
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