A) 1-hydroxybutane
B) 2-hydroxybutane
C) 2-hydroxy-2-methylpropane
D) 1-hydroxy-2-methylpropane
Correct Answer: C
Solution :
\[{{(C{{H}_{3}})}_{3}}C-OH+HCl\xrightarrow{Anhyd.\ ZnC{{l}_{2}}+HCl}\] \[{{(C{{H}_{3}})}_{3}}C-Cl+{{H}_{2}}O\] \[{{3}^{o}}\]reacts immediately \[{{(C{{H}_{3}})}_{3}}CH-OH+HCl\xrightarrow{Anhyd.\ ZnC{{l}_{2}}+HCl}\] \[{{(C{{H}_{3}})}_{2}}CH-Cl+{{H}_{2}}O\] \[{{2}^{o}}\]reacts after 5 min. \[C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}-OH+HCl\xrightarrow{Anhyd.\ ZnC{{l}_{2}}+HCl}\] \[C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}-Cl+{{H}_{2}}O\] \[{{1}^{o}}\]reacts only on heating.
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