JEE Main & Advanced Chemistry Haloalkanes and Haloarenes / हैलोएल्केन तथा हैलोएरीन्स Question Bank Properties of Halogen Containing Compounds

  • question_answer
    Reaction of t-butyl bromide with sodium methoxide produces [CBSE PMT 1994]

    A) Isobutane

    B) Isobutylene

    C) Sodium t-butoxide

    D) t-butyl methyl ether

    Correct Answer: B

    Solution :

               \[C{{H}_{3}}-\underset{C{{H}_{3}}}{\overset{C{{H}_{3}}}{\mathop{\underset{|\,\,\,\,\,\,}{\overset{|\,\,\,\,\,\,\,}{\mathop{C\,-\,}}}\,}}}\,Br+C{{H}_{3}}ONa\xrightarrow{\text{Elimination}}\]\[\underset{\text{Isobutylene}}{\mathop{C{{H}_{3}}-\overset{C{{H}_{3}}}{\mathop{\overset{|\,\,\,\,\,\,}{\mathop{C\,\,=\,}}\,}}\,C{{H}_{2}}}}\,+C{{H}_{3}}OH+NaBr\]                                                               \[C{{H}_{3}}ONa\to C{{H}_{3}}{{O}^{-}}+N{{a}^{+}}\] methoxide ion \[(C{{H}_{3}}{{O}^{-}})\] is a strong base, therefore it abstract proton from \[{{3}^{o}}\]alkyl halide and favours elimination reaction.


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