BCECE Engineering BCECE Engineering Solved Paper-2009

  • question_answer
    This metal is extracted from its ore by formation of a cyanide complex

    A)  \[Ag\]                 

    B)         \[Cu\]                 

    C)  \[Al\]                   

    D)         \[Zn\]

    Correct Answer: A

    Solution :

    Gold (Au) and silver (Ag) are extracted by treating their ores with dilute \[NaCN\] solution in the presence of air. During this process, a cyanide complex is formed which gives pure metal when treated with more electropositive metal like Zn. \[4\,Ag+8C{{N}^{-}}+2{{H}_{2}}O+{{O}_{2}}\]     \[\xrightarrow{{}}4{{[Ag\,{{(CN)}_{2}}]}^{-}}+4O{{H}^{-}}\] \[2{{[Ag\,(C{{N}_{2}})]}^{-}}+Zn\xrightarrow{{}}{{[Zn{{(CN)}_{4}}]}^{2-}}+\underset{\text{Silver}}{\mathop{2\,Ag}}\,\] This process is called Mac Arthur Forest process.


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