BCECE Medical BCECE Medical Solved Papers-2010

  • question_answer
    The order of decreasing Stability of the carbanions is \[{{(C{{H}_{3}})}_{3}}\overline{C}(1),\,{{(C{{H}_{3}})}_{2}}\overline{C}H(2)C{{H}_{3}}\overline{C}{{H}_{2}}(3)\], \[{{C}_{6}}{{H}_{5}}\overline{C}{{H}_{2}}(4)\]

    A)  \[1>2>3>4\]

    B)  \[4>3>2>2>1\]

    C)  \[1>2>4>3\]    

    D)  \[4>1>2>3\]

    Correct Answer: B

    Solution :

    The stability of the carbanion decreases with increase in number of alkyl groups. However, phenyl group stabilises the carbanion due to resonance effect. \[\therefore \] The order of stability of given ions is as follows \[{{C}_{6}}{{H}_{5}}\overline{C}{{H}_{2}}>C{{H}_{3}}\overline{C}{{H}_{2}}>{{(C{{H}_{3}})}_{2}}\overline{C}H>{{(C{{H}_{3}})}_{3}}\overline{C}\] or \[4>3>2>1\]


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