BCECE Medical BCECE Medical Solved Papers-2012

  • question_answer
    \[\Delta {{U}^{o}}\] of combustion of methane is\[-X\,k\,J\,mo{{l}^{-1}}\]. The value of \[\Delta {{H}^{o}}\] is

    A)  \[=\Delta {{U}^{o}}\]

    B)  \[>\Delta {{U}^{o}}\]

    C)  \[<\Delta {{U}^{o}}\]

    D)  = 0

    Correct Answer: C

    Solution :

    \[C{{H}_{4}}(g)+2{{O}_{2}}(g)\xrightarrow{{}}C{{O}_{2}}(g)+2{{H}_{2}}O(l)\]                 \[\Delta {{n}_{g}}=({{n}_{p}}-{{n}_{r}})=1-3=-2\]                 \[\Delta {{H}^{o}}=({{n}_{p}}-{{n}_{r}})=1-3=-2\] \[\Delta {{H}^{o}}=-X-2RT\]or \[\Delta {{H}^{o}}<\Delta {{U}^{o}}\]


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